Thin film solar cell with 8.4% power conversion efficiency using an earth-abundant Cu2ZnSnS4 absorber
- Journal
- Progress in Photovoltaics: Research and Applications
- Page
- 72 (2013)
- Year
- Before KAIST
- Link
- https://doi.org/10.1002/pip.1174 380회 연결
Using vacuum process, we fabricated Cu2ZnSnS4 solar cells with 8.4% efficiency, a number independently certified by an external, accredited laboratory. This is the highest efficiency reported for pure sulfide Cu2ZnSnS4 prepared by any method. Consistent with literature, the optimal composition is Cu-poor and Zn-rich despite the precipitation of secondary phases (e.g., ZnS). Despite a very thin absorber thickness (~600 nm), a reasonably good short-circuit current was obtained. Time-resolved photoluminescence measurements suggest a minority carrier-diffusion length on the order of several hundreds of nanometers and relatively good collection of photo-carriers across the entire absorber thickness.